(R)-(+)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl

产品介绍：

Technical Notes:

1. Ligand used in the ruthenium catalyzed, enantioselective hydrogenation of alkenes, carbonyls, and imines.

2.Ligand used in the rhodium-catalyzed cyclization of acetylenic aldehydes.

3.Ligand used in the iridium-catalyzed hydrogenative coupling of alkynes to aromatic and aliphatic N-arylsulfonyI aldimines.

4. Asymmetric Cu-catalyzed propargylic substitution with amines,«a and enamines.

5. Catalytic desymmetrizing intramolecular Heck reaction.

6.Assembly of 1 ,3- polyols .

7. Pd-catalyzed diastereo/enantioselective allylic alkylations of ketone enolates .

8. Enantioselective vinylogous Reformatsky-type addition.

9. Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron- substituted allylcopper complexes

and their In situ site-, diastereo-, and enantioselective additions to ketones .

Strem

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