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TyrannoPhos

品牌
Sigma-Aldrich
CAS
2097604-70-9
货号
902284
包装型号
规格纯度
参考价格
1802.32 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

This new aryl alkylphosphine ligand developed in Abby′s Doyle′s lab has been tailored specifically for nickel catalysis as demonstrated in the Suzuki coupling of acetals with boronic acids to generate benzylic ethers, reactions that pose challenges in Ni catalysis when using phosphine ligands developed for Pd-catalysed couplings.

其他说明

Parameterization of phosphine ligands demonstrates enhacement of nickel catalysis via remote steric effects

基本信息

经验(实验)分子式C33H51P
分子量478.73

产品性质

形式powder or crystals
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
官能团phosphine
SMILES stringCC(C1=CC(P(C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2)C3CCCC3)=CC(C(C)(C)C)=C1)(C)C

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

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