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4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl

4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧

品牌
Sigma-Aldrich
CAS
14691-89-5
货号
00375
规格纯度
purum, ≥98.0% (HPLC)
参考价格
528.48 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

一般描述

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by 1H, 13C and 15N NMR spectral data.

应用

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

其他说明

将醇轻度氧化成羰基的新型氧化剂

基本信息

经验(实验)分子式C11H21N2O2
分子量213.30
Beilstein3546225
EC 号423-840-3
MDL编号MFCD00043593
PubChem化学物质编号329747053
NACRESNA.22

产品性质

质量水平200
等级purum
测定≥98.0% (HPLC)
环保替代产品得分old score: 9
new score: 8
Find out more about DOZN™ Scoring
环保替代产品特性Waste Prevention
Safer Solvents and Auxiliaries
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.
mp143-145 ℃ (lit.)
143-146 ℃
环保替代产品分类Re-engineered
储存温度2-8℃
SMILES stringCC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
InChI1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
InChI keyUXBLSWOMIHTQPH-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
预防措施声明P264 - P270 - P301 + P312 + P330 - P501
危险分类Acute Tox. 4 Oral
储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves

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