(S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2,2-dimethyl-2,3-dihydrobenzo[d][1,3]oxaphosphole

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Technical Notes: L igand used with

1.Palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.

2.NickeI catalyst for asymmetric intramolecular/intermolecular reductive addition.

References:

1. Org. Lett. 2012, 14 , 2258 2261

2.J. Am. Chem. Soc., 2014, 136, 570- 573

3.Angew. Chem., Int. Ed. 2015, 54, 7144-7148

4.Adv. Synth. Catal. 2016, 358, 3522-3527

5.ACS Catal. 2018, 8, 10190-10209

6.Angew. Chem., Int. Ed. 2015, 54, 2520 -2524

7.Org. Chem. Front. 2015, 2, 1322-1325

Strem

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(S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2,2-dimethyl-2,3-dihydrobenzo[d][1,3]oxaphosphole

(S)-3-(叔丁基)-4-(2,6-二甲氧基苯基)-2,2-二甲基-2,3-二氢苯并[d][1,3]氧磷杂环戊烷