Technical Notes:
1.Sulfinamide phos phine organocatalyst for the enantioselective intramolecular Rauhut-Currier reaction.
2.Used in phosphine-catalyzed asymmetric intermolecular cross-vinylogous Rauhut-Currier Reactions of vinyl Ketones with para-quinone methides.
3.Used in the enantios elective phosphine-catalyzed allylic alkylations of mix-indene with MBH carbonates.
References:
1.Angew. Chem. Int. Ed. 2015, 54, 6874.
2.ACS Catal. 2017, 7, 2805.
3.Org. Lett. 2017, 19, 6080.