Technical Notes:
1.Catalyst for regio and stereo-specific ring opening via N- ) bond cleavage.
2.Catalyst for transformation of 1 ,6-enynes and diazoalkanes into alkenylbicyclo3.1 .Ohexane derivatives . Catalyst for ring closing enyne metathesis.
3.Catalyst for 2 + 2 + 2 cocyclization of diene-yne, and cyclodimerization of allenynes.
4.Catalyst for hydrovinylation of ynamides with ethylene .
5.Catalyst for c -H insertion reactions of carbenes .
References: 1.O rg. Lett., 2009, 11, 2077. 2.J. Am. Chem. Soc., 2007, 129, 6037. 3.Organometallics, 2008, 27, 6313. 4.J. Am. Chem. Soc., 2007, 129, 7730. 5.Organometallics, 2009, 28, 669. 6.Org. L ett., 2011, 13, 2718. 7.Angew. Chem. Int. Ed., 2012, 51, 723.