Technical Notes:
1. Supporting ligand in a chiral diamine ruthenium system for the enantiosele ctive hyd rogenation of ketones.
2. Useful ligand for palladium-catalyzed amination and Kumada cross coupling reactions
3.Useful ligand for palladium-catalyzed synthesis of butatrenes.
4.Useful ligand for iridium-catalyzed c-c cross-coupling of allenes with primary alcohols via transfer hydrogenation
5.Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hyd rogenation.
6.Useful ligand for iridium- catalyzed C-C cross coupling of allylic gem dicarboxylates with aldehydes via transfer hydrogenation. Useful ligand for the palladium catalyzed synthesis of chiral allenylsilanes.
7.Ruthenium- catalyzed synthesis of indoles
8.Ruthenium-catalyzed oxidative cyclization .
9Rhodium catalyzed boron arylation.
