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(S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin

(S)-(+)-1,13-双(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二恶任英

品牌
Strem
CAS
486429-99-6
货号
15-0176
包装型号
规格纯度
95%
参考价格
1770 *本价格含增值税费
促销
数量
-+
产品介绍:

Technical Notes:

1. New generation of chiral biaryl phosphine ligands with tunable dihedral angles. The ability to

modify the dihedral angle allows for the fine tuning of the catalyst system and optimization of en antioselectivity.

2.Ru-C3-TUNEPHOS complexes are used for asymmetric hydrogenation of ß-ketoesters ', enol acetates?, cyclic ß-amino acids3, a-phthalimide ketones, and a-keto esters.

3.Rh-catalyzed hydroformylation of cyclopropenes .

References:

1.J. Org. Chem., 2000, 65, 6223.

2.Org. Lett., 2002, 4, 4495.

3.J. Am. Chem. Soc., 2003, 125, 9570.

4.J. Am. Chem. Soc., 2004, 126, 1626.

5.Synlett 2006, 126, 1 169

6.J. Am. Chem. Soc., 2008, 130, 13804.

Strem

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