产品说明
应用
PhPAd-DalPhos Ni(o-tolyl)Cl is an air stable precatalyst developed in the Stradiotto lab used for coupling of bulky primary amines with arenes.
其他说明
Technology Spotlight: DalPhos ligands
PhPAd-DalPhos: Ligand-Enabled, Nickel-Catalyzed Cross-Coupling of (Hetero)aryl Electrophiles with Bulky Primary Alkylamines
基本信息
经验(实验)分子式 | C35H37ClNiO3P2 |
分子量 | 661.76 |
产品性质
测定 | ≥95% |
形式 | powder |
mp | 235-248 ℃ |
SMILES string | Cl[Ni]1(P(C(C2)(O3)C)(C4=CC=CC=C4P(C5=CC=CC=C5)1C6=CC=CC=C6)[C@@](C[C@]3(OC27C)C)(O7)C)C(C=CC=C8)=C8C |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H302 + H332 - H334 - H341 - H351 - H361f - H372 - H410 |
预防措施声明 | P202 - P260 - P264 - P273 - P301 + P312 - P308 + P313 |
危险分类 | Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - STOT RE 1 |
储存分类代码 | 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |