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PBDB-T-SF

Poly[(2,6-(4,8-bis(5-(2-ethylhexylthio)-4-fluorothiophen-2-yl)-benzo[1,2-b:4,5-b′]dithiophene))-alt-(5,5-(1′,3′-di-2-thienyl-5′,7′-bis(2-ethylhexyl)benzo[1′,2′-c:4′,5′-c′]dithiophene-4,8-dione)]

品牌
Sigma-Aldrich
货号
906344
包装型号
规格纯度
Mw ≥80,000
参考价格
5013.89 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

PBDB-T-SF is a fluorinated wide-bandgap polymeric donor (n-type semiconductor) with relatively deep highest occupied molecular orbital (HOMO) energy level. It has been used in high performance polymer organic solar cells (PSCs).
HOMO =−5.40eV
LUMO =−3.60eV

Polymer organic solar cells (PSCs) device performance:

Device based on PBDB-T-SF:NCBDT-4Cl
Before any post-treatment
PCE= of 13.1%
After device optimizations
Voc = 0.85V
Jsc = 2.35 mA /cm2
FF = 74.3%
PCE >14%
Energy loss = 0.55 eV

The improved performance was attributed to the more efficient photo-electron conversion process in the optimal device.

Device performance based on PBDB-T-SF:ITIC-F as active layer
(ITO)/ZnO/active layer/MoO3/Al
Voc = 0.88 V
Jsc = 20.50 mA/cm2
FF = 71.9%
PCE = 13.1%
Energy loss = 0.66 eV

基本信息

线性分子式(C68H76F2O2S10)n

产品性质

描述Band gap: 1.8 eV
形式granular
分子量Mw ≥80,000
颜色 purple, Shine
溶解性chlorobenzene: soluble
chloroform: soluble
soluble (o-dichlorobenzene)
轨道能量HOMO -5.4 eV 
LUMO -3.6 eV 
PDI~2.5

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

Sigma-Aldrich

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