产品说明
应用
(S)-2-(Methoxydiphenylmethyl)pyrrolidine is a diphenylprolinol methyl ether, which can be used as a catalyst to synthesize:
- Enantioselective ketones via intermolecular asymmetric Michael addition of aldehydes to nonactivated enones.
- Stereoselective chiral bipyrazolidin-3-one derivatives by dipolar cycloaddition reaction of azomethine imines with α, β-unsaturated aldehydes.
- Enantioenriched spiro nitrogen heterocycles via asymmetric nucleophilic epoxidation of α-ylideneoxindole esters.
- Optically active secondary alcohols by asymmetric addition of Et2Zn to various aldehydes.
包装
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.
基本信息
经验(实验)分子式 | C18H21NO |
分子量 | 267.37 |
MDL编号 | MFCD09750440 |
PubChem化学物质编号 | 24885069 |
NACRES | NA.22 |
产品性质
测定 | 95% (HPLC) |
光学纯度 | ee: ≥99.5% (HPLC) |
储存温度 | 2-8℃ |
SMILES string | COC([C@@H]1CCCN1)(c2ccccc2)c3ccccc3 |
InChI | 1S/C18H21NO/c1-20-18(17-13-8-14-19-17,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17,19H,8,13-14H2,1H3/t17-/m0/s1 |
InChI key | CGUGCZSRPDCLBT-KRWDZBQOSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H302 |
危险分类 | Acute Tox. 4 Oral |
储存分类代码 | 12 - Non Combustible Liquids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |