产品介绍：
产品说明
应用
(S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize:
- Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles.
- Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et2Zn) to cyclic enones.
- Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.
包装
50, 250 mg in amber glass bottle
基本信息
| 经验(实验)分子式 | C33H32NO2P |
| 分子量 | 505.59 |
| MDL编号 | MFCD08459342 |
| PubChem化学物质编号 | 329762229 |
| NACRES | NA.22 |
产品性质
| 测定 | 97% |
| 形式 | powder |
| 旋光性 | [α]22/D −65.0°, c = 1 in chloroform |
| mp | 120-125 ℃ |
| 储存温度 | −20℃ |
| SMILES string | C[C@@H](N([C@H](C)c1ccccc1)P2Oc3cccc4CCC5(CCc6cccc(O2)c56)c34)c7ccccc7 |
| InChI | 1S/C33H32NO2P/c1-23(25-11-5-3-6-12-25)34(24(2)26-13-7-4-8-14-26)37-35-29-17-9-15-27-19-21-33(31(27)29)22-20-28-16-10-18-30(36-37)32(28)33/h3-18,23-24H,19-22H2,1-2H3/t23-,24-,33?/m1/s1 |
| InChI key | ZXLQLIDJAURBDD-HRPAVAKOSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 - H319 - H335 |
| 预防措施声明 | P261 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 储存分类代码 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
