产品介绍：
产品说明
应用
脱氢氨基酸、甲酯和酮的不对称氢化反应的有效配体。
(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane may be used as a ligand in the following processes:
- Enantioselective reductive cyclization of 1,6-enynes via asymmetric hydrogenation in the presence of a rhodium catalyst to form alkylidene-substituted heterocycles.
- Asymmetric hydroboration of 3,3-disubstituted cyclopropenes to form 2,2-disubstituted cyclopropyl boronates.
- Asymmetric ring-opening reactions of azabenzonorbornadienes in the presence of zinc(II) triflate and palladium(II) acetate to form aminodihydronaphthalenes.
包装
100 mg in clear glass bottle
500 mg in amber glass bottle
法律信息
与 Johnson Matthey Catalyst 联合销售，仅供研究使用。适用美国专利 US5874629 以及由此产生的专利。
基本信息
| 经验(实验)分子式 | C40H34P2 |
| 分子量 | 576.65 |
| MDL编号 | MFCD03094575 |
| PubChem化学物质编号 | 24885681 |
产品性质
| 测定 | 96% |
| 旋光性 | [α]/D -34±4°, c = 1 in chloroform |
| mp | 222-226 ℃ |
| InChI | 1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2 |
| InChI key | GYZZZILPVUYAFJ-UHFFFAOYSA-N |
安全信息
| 储存分类代码 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
