产品介绍：
产品说明
应用
Chiral Bronsted acid demonstrated in Mukaiyama aldol reactions and Friedel-Crafts alkylation of indoles with sulfonyl imines. Precursor to chiral fluorinating reagent.
A Powerful Chiral Counteranion Motif for Asymmetric Catalysis
Chiral Sulfonimide as a Brønsted Acid Organocatalyst for Asymmetric Friedel-Crafts Alkylation of Indoles with Imines
Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination
包装
100 mg in clear glass bottle
500 mg in amber glass bottle
基本信息
| 经验(实验)分子式 | C36H17F12NO4S2 |
| 分子量 | 819.64 |
| MDL编号 | MFCD28009151 |
| PubChem化学物质编号 | 329768237 |
| NACRES | NA.22 |
产品性质
| 测定 | 95% |
| 旋光性 | [α]22/D -42.0°, c = 0.5% in chloroform |
| reaction suitability | reaction type: Aldol Reaction reaction type: Allylation reaction type: Carbonyl/Imine Addition reaction type: Friedel-Crafts Alkylation |
| mp | 325-330 ℃ |
| SMILES string | FC(F)(F)c1cc(cc(c1)C(F)(F)F)-c2cc3ccccc3c4-c5c(c(cc6ccccc56)-c7cc(cc(c7)C(F)(F)F)C(F)(F)F)S(=O)(=O)NS(=O)(=O)c24 |
| InChI | 1S/C36H17F12NO4S2/c37-33(38,39)21-9-19(10-22(15-21)34(40,41)42)27-13-17-5-1-3-7-25(17)29-30-26-8-4-2-6-18(26)14-28(32(30)55(52,53)49-54(50,51)31(27)29)20-11-23(35(43,44)45)16-24(12-20)36(46,47)48/h1-16,49H |
| InChI key | DFXCMPXSCANWFA-UHFFFAOYSA-N |
安全信息
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
