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(R,S)-Bode Kinetic Resolution Catalyst

品牌
Sigma-Aldrich
CAS
1394957-71-1
货号
804568
包装型号
规格纯度
参考价格
947 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

The following hydroxamic acid catalyst was shown by Bode and coworkers to assist in the kinetic resolution of cyclic amines through acylation of one enantiomer, which can be controlled using either the (R or S)- or (S or R)-Bode Kinetic Resolution Catalyst, both of which are also available through sigma-aldrich.
It can also be employed in the preparation of nonracemic piperidines by kinetic resolution using an α-hydroxy-α′, β-unsaturated ketone in the presence of a pyrrolotriazolium salt.

包装

100 mg in glass bottle

其他说明

Expanded substrate scope and catalyst optimization for the catalytic kinetic resolution of N-heterocycles

基本信息

经验(实验)分子式C11H10BrNO3
分子量284.11
PubChem化学物质编号329768882
NACRESNA.22

产品性质

质量水平100
储存温度15-25℃
SMILES stringO=C(CO1)N(O)[C@@]2([H])[C@]1([H])CC3=CC=C(Br)C=C32
InChI1S/C11H10BrNO3/c12-7-2-1-6-3-9-11(8(6)4-7)13(15)10(14)5-16-9/h1-2,4,9,11,15H,3,5H2/t9-,11+/m0/s1
InChI keyFQXSUQCCAHKURK-GXSJLCMTSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
预防措施声明P301 + P312 + P330
危险分类Acute Tox. 4 Oral
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

Sigma-Aldrich

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