产品介绍:
产品说明
应用
1-Tetradecene can be used as a reactant to synthesize:
- 2-Tetradecanone via PdCl2/CrO3 catalyzed oxidation reaction.
- (E)-ethyl pentadec-2-enoate, which is used as a key intermediate in the diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid via Johnson-Claisen rearrangement.
It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.
包装
25 mL in glass bottle
基本信息
线性分子式 | CH3(CH2)11CH=CH2 |
分子量 | 196.37 |
Beilstein | 1701156 |
EC 号 | 214-306-9 |
MDL编号 | MFCD00008981 |
PubChem化学物质编号 | 57653175 |
NACRES | NA.22 |
产品性质
蒸汽密度 | 6.8 (vs air) |
质量水平 | 100 |
测定 | ≥97.0% (GC) |
自燃温度 | 455 °F |
折射率 | n n |
bp | 251 ℃ (lit.) |
mp | −13-−11 ℃ (lit.) |
密度 | 0.775 g/mL at 25 ℃ (lit.) |
SMILES string | CCCCCCCCCCCCC=C |
InChI | 1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3 |
InChI key | HFDVRLIODXPAHB-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H304 |
预防措施声明 | P301 + P310 - P331 - P405 - P501 |
危险分类 | Asp. Tox. 1 |
补充剂危害 | EUH066 |
储存分类代码 | 10 - Combustible liquids |
WGK | WGK 3 |
闪点(F) | 230.0 °F |
闪点(C) | 110 ℃ |
个人防护装备 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |