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1-Tetradecene

1-十四烯

品牌
Sigma-Aldrich
CAS
1120-36-1
货号
87189
包装型号
规格纯度
≥97.0% (GC)
参考价格
720.84 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

1-Tetradecene can be used as a reactant to synthesize:

  • 2-Tetradecanone via PdCl2/CrO3 catalyzed oxidation reaction.
  • (E)-ethyl pentadec-2-enoate, which is used as a key intermediate in the diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid via Johnson-Claisen rearrangement.

It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.

包装

25 mL in glass bottle

基本信息

线性分子式CH3(CH2)11CH=CH2
分子量196.37
Beilstein1701156
EC 号214-306-9
MDL编号MFCD00008981
PubChem化学物质编号57653175
NACRESNA.22

产品性质

蒸汽密度6.8 (vs air)
质量水平100
测定≥97.0% (GC)
自燃温度455 °F
折射率n20/D 1.436 (lit.)
n20/D 1.436
bp251 ℃ (lit.)
mp−13-−11 ℃ (lit.)
密度0.775 g/mL at 25 ℃ (lit.)
SMILES stringCCCCCCCCCCCCC=C
InChI1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3
InChI keyHFDVRLIODXPAHB-UHFFFAOYSA-N

安全信息

象形图GHS08
警示用语:Danger
危险声明H304
预防措施声明P301 + P310 - P331 - P405 - P501
危险分类Asp. Tox. 1
补充剂危害EUH066
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)230.0 °F
闪点(C)110 ℃
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Sigma-Aldrich

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