产品说明
一般描述
旋光度偏差 ± 13
应用
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
(R,R)-i-Pr-DUPHOS is a chiral phospholane class of ligand that can be used in:
- The catalytic asymmetric hydrogenation reactions.
- Rhodium catalyzed enantioselective synthesis of 1,2 diols via asymmetric intramolecular hydrosilylation of α- and β-hydroxyketones.
- In the enantioselective synthesis of diarylmethanols by arylation of aromatic aldehydes with arylboronic acids in the presence of a rhodium catalyst.
包装
100 mg in clear glass bottle
500 mg in amber glass bottle
法律信息
与 Kanata Chemical Technologies Inc. 联合销售,仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售,此许可不包括利用这些化合物制备在制药领域销售的产品的权利。
基本信息
经验(实验)分子式 | C26H44P2 |
分子量 | 418.58 |
MDL编号 | MFCD02684549 |
PubChem化学物质编号 | 24884989 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
旋光性 | [α]20/D +103°, c = 1 in chloroform |
折射率 | n |
SMILES string | CC(C)[C@H]1CC[C@H](C(C)C)P1c2ccccc2P3[C@H](CC[C@@H]3C(C)C)C(C)C |
InChI | 1S/C26H44P2/c1-17(2)21-13-14-22(18(3)4)27(21)25-11-9-10-12-26(25)28-23(19(5)6)15-16-24(28)20(7)8/h9-12,17-24H,13-16H2,1-8H3/t21-,22-,23-,24-/m1/s1 |
InChI key | RBVGOQHQBUPSGX-MOUTVQLLSA-N |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | 230.0 °F |
闪点(C) | > 110 ℃ |
个人防护装备 | Eyeshields, Gloves, type N95 (US) |