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2-Chloro-1-methylpyridinium Iodide

2-氯-1-甲基吡啶碘化物

品牌
Sigma-Aldrich
CAS
14338-32-0
货号
198005
规格纯度
97%
参考价格
343.81 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

一般描述

2-Chloro-1-methylpyridinium iodide (Mukaiyama reagent), is a commonly used reagent in organic synthesis for the activation of the hydroxy group of alcohols and carboxylic acids. It is used to synthesize derivatives of esters, lactones, amides, lactams, and ketenes from the corresponding carboxylic acids. It is also used as an efficient coupling reagent in the synthesis of peptides because of its low toxicity, simple reaction conditions, and also less expensive than EDC.

应用

2-Chloro-1-methylpyridinium iodide (CMPI) can be used as:

  • A dehydrating agent for the conversion of various aldoximes to nitriles, and alcohols into alkyl thiocyanates.
  • A cross-linking agent to fabricate biodegradable cross-linked hyaluronic acid film and gelatin membranes for biomedical applications.
  • A condensing agent to synthesize various β-lactams from β-amino acids.

包装

10, 25, 100 g in glass bottle

基本信息

经验(实验)分子式C6H7ClIN
分子量255.48
Beilstein3572320
EC 号238-288-7
MDL编号MFCD00011984
PubChem化学物质编号24851856
NACRESNA.22

产品性质

质量水平200
测定97%
mp200 ℃ (dec.) (lit.)
SMILES string[I-].C[n+]1ccccc1Cl
InChI1S/C6H7ClN.HI/c1-8-5-3-2-4-6(8)7;/h2-5H,1H3;1H/q+1;/p-1
InChI keyABFPKTQEQNICFT-UHFFFAOYSA-M

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves

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