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Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)

三氯氧代 [(二甲基硫醚)三苯基膦氧化物] 铼 (V)

品牌
Sigma-Aldrich
CAS
108695-90-5
货号
665096
包装型号
规格纯度
97%
参考价格
613.71 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

Catalyst for:

  • Enantioselective reduction of ketones and imines
  • Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
  • Synthesis of 2-deoxy-α glycosides
  • Sulfurization of phosphorous(III) compounds with thiiranes

Reactant for synthesis of mono and dinuclear compounds
Reagent for rhenium-cyclized somatostatine derivative series synthesis

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

经验(实验)分子式C20H21Cl3O2PReS
分子量648.98
MDL编号MFCD08276862
PubChem化学物质编号24884712
NACRESNA.22

产品性质

质量水平100
测定97%
形式powder
reaction suitabilitycore: rhenium
reagent type: catalyst
SMILES stringCSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3
InChI keyGIBDGLAUIKUJJX-UHFFFAOYSA-K

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves

Sigma-Aldrich

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