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tert-Butyldiphenylphosphine

叔丁基二苯基膦

品牌
Sigma-Aldrich
CAS
6002-34-2
货号
591688
包装型号
规格纯度
97%
参考价格
849.31 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

Catalyst for:

  • Nickel/Lewis acid-catalyzed carbocyanation of alkynes with acetonitrile or substituted acetonitriles
  • Palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions
  • Palladium to form a catalyst for methoxycarbonylation reactions
  • Ru-catalyzed transfer hydrogenation in reductive coupling of disubstituted allenes with aldehydes
  • Stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes
  • Phosphine ligand in nickel-catalyzed carbocyanation of alkynes
  • Monodentate P-Donor Ligands (LKB-P)

包装

1, 5 g in glass bottle

基本信息

线性分子式(C6H5)2PC(CH3)3
分子量242.30
EC 号227-848-6
MDL编号MFCD00015004
PubChem化学物质编号24881351
NACRESNA.22

产品性质

质量水平100
测定97%
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
bp144-146 ℃/2 mmHg (lit.)
mp52-57 ℃ (lit.)
官能团phosphine
SMILES stringCC(C)(C)P(c1ccccc1)c2ccccc2
InChI1S/C16H19P/c1-16(2,3)17(14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3
InChI keyQZUPHAGRBBOLTB-UHFFFAOYSA-N

安全信息

储存分类代码12 - Non Combustible Liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Sigma-Aldrich

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