产品说明
一般描述
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.
应用
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:
- metal ketimines to form enantiopure sulfinimines
- p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine
包装
10 g in glass bottle
基本信息
经验(实验)分子式 | C17H26O2S |
分子量 | 294.45 |
Beilstein | 3207468 |
PubChem化学物质编号 | 24856828 |
NACRES | NA.22 |
产品性质
质量水平 | 200 |
测定 | 98% |
旋光性 | [α]20/D −195°, c = 2 in acetone |
mp | 102-104 ℃ (lit.) |
储存温度 | −20℃ |
SMILES string | C[C@@H]1CC[C@@H](C(C)C)[C@@H](C1)OS(=O)c2ccc(C)cc2 |
InChI | 1S/C17H26O2S/c1-12(2)16-10-7-14(4)11-17(16)19-20(18)15-8-5-13(3)6-9-15/h5-6,8-9,12,14,16-17H,7,10-11H2,1-4H3/t14-,16+,17-,20+/m1/s1 |
InChI key | NQICGNSARVCSGJ-ASKNOMKYSA-N |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | Eyeshields, Gloves, type N95 (US) |