应用
Hexamethylphosphorous triamide is used as a reagent in organic synthesis as a phosphorylating agent. It is associated with carbon tetrachloride for the substitution of hydroxy groups with chlorides. It is involved in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the preparation of carbonates as well as reduction of ozonides.
备注
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
基本信息
MDL
MFCD00008301
EINECS
216-534-4
分子式
[(CH3)2N]3P
分子量
163.21
熔点
-44°
沸点
162-164°
闪点
37°(98°F)
密度
0.898
折射率
1.4650
灵敏度
Air Sensitive. Store under Nitrogen. May form a Precipitate. Ambient temperatures.
形态
Liquid
溶解性
Miscible with water.
Beilstein
906778
GHS危害和防范说明
GHS符号
Hazard Statements
H226-H340-H350
Flammable liquid and vapour.May cause genetic defects.May cause cancer.
Precautionary Statements
P210-P201-P280-P303+P361+P353-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Obtain special instructions before use.Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
3
包装组
III
危险类别
45-46-10
May cause cancer.May cause heritable genetic damage.Flammable.
安全等级
53-45
Avoid exposure - obtain special instructions before use.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
RTECS
TH3390000
TSCA
是