应用
Copper(I) iodide is used as a catalyst in organic synthesis, cathode ray tube coating, cloud seeding, and as temperature indicator with HgI2. It catalyzes the conversion of aryl, heteroaryl, and vinyl bromides into the corresponding iodides, which are employed in coupling reactions such as Suzuki, Stille, Sonogashira, Heck and Ullmann reactions.
备注
It is generally stable in air and is photosensitive.
基本信息
MDL
MFCD00010978
EINECS
231-674-6
分子式
CuI
分子量
190.45
熔点
605°
沸点
ca 1290°
密度
5.63
折射率
2.346
灵敏度
Moisture Sensitive. Air Sensitive. Light Sensitive. Store under Nitrogen. Ambient temperatures.
形态
Chunks/powder
溶解性
Copper(I) iodide is soluble in ammonia, thiosulfate, sodium and potassium iodide solutions. Insoluble in water and dilute acids.
Merck
14,2662
GHS危害和防范说明
GHS符号
Hazard Statements
H302-H315-H319-H335-H400-H410
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.
Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
9
包装组
III
危险类别
22-36/37/38-50/53
Harmful if swallowed.Irritating to eyes, respiratory system and skin.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
安全等级
26-36/37-57-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste
欧盟危险品标志
TSCA
是