应用
tert-Butyl isocyanide is used in a tin-free procedure for alkyl radical reactions in the presence of a free-radical initiator. It is a useful intermediate in multicomponent reactions. It is also used in the synthesis of coumarines, 4H-chromenes, isoxazolines and to trap 2-cyclopropylidene-1,3-diones.
备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents.
基本信息
MDL
MFCD00000002
EINECS
230-553-5
分子式
C5H9N
分子量
83.13
沸点
90-92°
闪点
-2°(28°F)
密度
0.735
折射率
1.3755
灵敏度
Store at -20°C.
形态
Liquid
溶解性
Soluble in organic solvents such as ethanol, methanol, ether, toluene and dichloromethane.
Beilstein
1903156
GHS危害和防范说明
GHS符号
Hazard Statements
H225-H330
Highly flammable liquid and vapour.Fatal if inhaled.
Precautionary Statements
P210-P303+P361+P353-P304+P340-P320-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Specific treatment is urgent (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
3
包装组
II
危险类别
11-23
Highly flammable.Toxic by inhalation.
安全等级
9-20-36-45
Keep container in a well-ventilated place.When using do not eat or drink.Wear suitable protective clothing.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
欧盟危险品标志
RTECS
EQ7102500
TSCA
否
