应用
Benzyl phenyl ether reacts with aluminum bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane. It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal. Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported. Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated. Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities.
备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.
基本信息
MDL
MFCD00020660
分子式
C6H5CH2OC6H5
分子量
184.24
熔点
37-40°
沸点
286-287°
闪点
>110°(230°F)
灵敏度
Ambient temperatures.
形态
Crystalline solid
溶解性
Insoluble in water.
Beilstein
2045713
安全信息
TSCA
否
