应用
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
备注
Moisture sensitive. Incompatible with oxidizing agents.
基本信息
MDL
MFCD00054932
分子式
C13H25NSi
分子量
223.44
沸点
78°/0.4mm
闪点
106°(222°F)
密度
0.904
折射率
1.4920
灵敏度
Moisture Sensitive. Ambient temperatures.
形态
Liquid
溶解性
Not miscible in water.
Beilstein
3540663
GHS危害和防范说明
GHS符号
Hazard Statements
H302
Harmful if swallowed.
Precautionary Statements
P280f
Wear protective clothing.
安全信息
危险类别
22
Harmful if swallowed.
安全等级
36
Wear suitable protective clothing.
欧盟危险品标志
TSCA
否