Technical Notes:
1.Ligand for the Au-catalyzed asymmetric intramolecular cyclization of N-allenamides for the synthesis of chiral tetrahydrocarbolines.
2.Ligand for the Pd-catalyzed enantioselective intermolecular denitrogenative cyclization of benzotriazoles with allenes and N-allenamides .
References:
1. Angew. Chem. Int. Ed. 2017, 56, 15905.
2.Angew. Chem. Int. Ed. 2019, 58, 1 1444.