4-((1R,3R,5S,7R)-1,3,5-Triaza-7-phosphaadamantan-1-ium-1-yl)butane-1-sulfonate

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Technical Notes:

1.L igand for the low temperature thioetherification of chloro(hetero )arenes.8

2.L igand used in the efficient Pd catalyzed C-H (hetero )arylation of 1,3,4-0xadiazoles using

bromo(hetero )arenes.9

3.L igand used in the Pd catalyzed low temperature etherification of chloroheteroarenes.10

4.L igand used for the water soluble catalytic system for the Pd catalyzed amination of 6-chloropurine ribonucleoside and synthesis of alogliptin.1 1

5.L igand for the Pd catalyzed room temperature amination of heteroarenes .12

6.Versatile L igand for Suzuki-Miyaura, Sonogashira and Heck Reactions of Nucleosides.1 3

7.Ligand for the for the aminocarbonylation of nucleosides

8.L igand for the modification of Nucleosides and Heteroarenes.1,6

References:

1.Chem. Rec. 2021 21188-203

2.Curr. Protoc. Nucleic Acid Chem. 2020. 83. e117.

3.Synthesis PSP 2020.52 3595-3603

4.New J Chem 2020 14744-147 54.

Strem

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4-((1R,3R,5S,7R)-1,3,5-Triaza-7-phosphaadamantan-1-ium-1-yl)butane-1-sulfonate

4-((1R,3R,5S,7R)-1,3,5-三氮杂-7- 磷金刚烷 -1-鎓-1-基)丁烷-1-磺酸盐