(11bS)-4-Oxide-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-2,6-bis(2,3,4,5,6-pentafluorophenyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

产品介绍：

Technical Notes：

1.Chiral Brønsted acid catalysis for enantioselective Hosomi-Sakurai reaction of imines with allyltrimethylsilane .

2.Chiral Brønsted acid catalysis for stereoselective Mannich-type reactions of in situ generated C-alkynyl imines with ß-keto esters.

3.Chiral Brønsted acid catalysis for Mannich-type reaction of N-Boc-iminium intermediates, generated in situ from N-Boc- aminals.

References:

1. Org. Lett., 2011, 13, 2126.

2.Angew. Chem. Int. Ed. 2013, 52, 1 1509.

3.Tetrahedron, 2016, 72, 3687.

Strem

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