Technical Notes:

1.Precatalyst for the enantioselective hydrosilylation of olefins.

2.Precatalyst for asymmetric allylic alkylation and amination.

3.Used as a palladium source for cross-coupling reactions .

4. Can be used with Trost ligands.

5. Catalyst for the carbostannylation of alkynes.

6. Used as a precatalyst for a-arylation of aldehydes.

References:

1.J. Am. Chem. Soc., 1991, 1 13, 9887.

2.Tetrahedron, 1994, 50, 335.

3.J. Am. Chem. Soc., 2007, 129, 7718.

4. Org. L ett., 2007, 9, 4295.

5. Org. L ett., 2008, 10, 501.

6. Org. L ett., 2005, 7, 945.

7.Synlett, 2005, 2057

8. Tetrahedron, 2007, 63, 9393.

9. J. Am. Chem. Soc., 2006, 128, 2540.

10.Org. L ett., 2006, 8, 2027.

11.Angew. Chem. Int. Ed., 2007, 46, 6123.

12.J. Am. Chem. Soc., 1998, 120, 2975.

13.Angew. Chem. Int. Ed., 2008, 47, 2127.

14.Chem. Rev., 1996, 96, 395. (review)

15.Science of Synthesis, 2002, 1, 1 13.