Technical Notes:
1. Catalyst for insertion into c-H and X-H bonds.
2.Catalyst for Ylide generation.
3.Doyle-Kirmse Reaction of Allylic 4.Sulfides with DiazoalkaneClaisen rearrangement..
5Epoxides from aldehydes.
6. Synthesis of aziridines from allylic N-tosyloxycarbamates
7.Rh/NHC catalyzed direct intermolecular arylation of C-H bonds.
8.Chiral Bronsted acid-Rh catalyzed three component reactions of diazo compounds with alcohols and imines.
9. Rh-catalyzed cyclopropenations of ynamides .
10.Tandem asymmetric aza-Darzens/ring-opening reactions .