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(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

1,2-双[(2S,5S)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸铑(I)

品牌
Strem
CAS
849950-53-4
货号
45-0202
规格纯度
min. 98%
参考价格
1543 *本价格含增值税费
促销
数量
-+
产品介绍:

Technical Notes:

1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.

2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.

3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.

4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.

References:

1. Org. Lett., 2003, 5, 1273.

2. Tetrahedron Lett, 2004, 45, 9277.

3. Angew. Chem. Int. Ed., 2005, 44, 5834.

Strem

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