Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(mu-Cl)3]

产品介绍：

Technical Notes :

1. Biaryl bisphosphine ligand. The Ha-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturate carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)

2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug lbuprofen.

References:

1. J. Org. Chem.. 1996. 61. 5510

2. Topics Organometal. Chem. 2004, 6. 63 (review).

Strem

推荐产品

氯羰基氢化[4,5-双-(二-异丙基膦基)吖啶]钌(II), Chlorocarbonylhydrido[4,5-bis-(di-i-propylphosphinomethyl)acridine]ruthenium(II)

[1,3-双(2,6-二异丙基苯基)咪唑烷-2-亚基][(2-((1-甲氧基(甲基)氨基)-1-氧代丙-2-基)氧基]亚苄基二异戊烯(II),GreenCat-I2, [1,3-Bis(2,6-di-i-propylphenyl)imidazolidin-2-ylidene][(2-((1-methoxy(methyl)amino)-1-oxopropan-2-yl)oxy]benzylidenediiodoruthenium(II) GreenCat-I2

Hexakis[mu-(acetato-O:O')]-triaqua-mu3-oxotriruthenium(III)

六-[-(乙酸离子-O:O')]-三水-3-氧代三钌(Ⅲ)

1,3-双(2,6-二异丙基苯基)咪唑烷-2-亚基)(2-异丙氧基-5-硝基亚苄基)二氯化钌(II),Nitro-GrelaSiPr, 1,3-Bis(2,6-di-i-propylphenyl)imidazolidin-2-ylidene)(2-i-propoxy-5-nitrobenzylidene) ruthenium(II) dichloride Nitro-Grela SiPr

[1,3-双(2,6-二异丙基苯基)咪唑烷-2-亚基)(三环己基膦)-(2-氧代亚苄基)氯化钌(II),LatMetSIPr, [1,3-Bis(2,6-di-i-propylphenyl)imidazolidin-2-ylidene)(tricyclohexylphosphine)-(2-oxobenzylidene)ruthenium(II) chloride LatMet SIPr

二氯[(R)-(+)-2,2'-双(二苯基膦基)-1,1'-联萘][(S)-(+)-2-(α'-甲基甲胺)-1H-苯并咪唑]钌 (II), Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(S)-(+)-2-(α;-methylmethanamine)-1H-benzimidazole]ruthenium(II)

二氯[(S)-(-)-2,2'-双(二-对-甲苯基膦基)-1,1'-联萘[(S)-(-)-2-(α-(叔丁基)甲胺)-1H-苯并咪唑]钌(II), Dichloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl][(S)-(-)-2-(alpha-(t-butyl) methanamine)-1H-benzimidazole]ruthenium(II)

六氰基钌酸四钾盐水合物, Potassium hexacyanoruthenate(II) hydrate

Ruthenium(IV) oxide hydrate

氧化钌(IV)水合物

氯(均三甲苯)[(1S,2S)-(+)-2-氨基-1,2-二苯乙基(甲磺酰氨基)]钌(II), Chloro(mesitylene)[(1S,2S)-(+)-2-amino-1,2-diphenylethyl(methylsulfonylamido)]ruthenium(II) RuCl(mesitylene)[(S,S)-MsDpen]

Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(mu-Cl)3]

二甲基氨基二氯三(μ-氯)双[(R)-(+)-2,2'-双(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘]二钌(Ⅱ)