Technical Note:
1. Catalyst system used for asymmetric hydrogenation.
Strem
N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (R,R)-Ts-DENEB
氯{(S)-(-)-2,2'-双[二(3,5-二甲苯基)膦基] -1,1'- 联萘基}[(2S)-(+)-1-(4-甲氧基苯基)-1(4-甲氧基苯基-KC)-3-甲基-1,2-丁二胺]钌(II), Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1-(4-methoxyphenyl)-1’-(4-methoxyphenyl-kC)-3-methyl-1,2-butanediamine]ruthenium(II) (S)-RUCY?-XylBINAP
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
二氯化[(S)-(-)-2,2'-双(二苯基磷)-1,1'-联萘]钌
二氯双[(2-丙基膦)乙基胺]钌(II), Dichlorobis[2-(di-i-propylphosphino)ethylamine]ruthenium(II)
Dichloro(p-cymene)tricyclohexylphosphineruthenium(II)
对异丙苯基三环己基磷二氯化钌
二甲基二氯三(μ-氯双[(R)-(+)-2,2'-双(二苯基膦基)-1,1' -联萘] 二钌(II)[NH2Me2][{RuCl((R)-binap)} 2(μ-Cl)3], Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3]
二甲基铵二氯三(μ-氯)双[(S)-(-)-5,5'-双(二苯基膦基)-4,4'-联-1,3-苯并二恶唑]二钌酯(II)[NH2Me2][{RuCl((S)-SEGPHOS®)}2(μ-Cl)3], Dimethylammonium dichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos?)}2(mu-Cl)3]
二[(S)-(+)-5,5'-双(二苯基膦)-4,4'-双-1,3 -二氧基苯, Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos?)}2(mu-Cl)3]
Hexaammineruthenium(III) chloride
三氯化六铵合钌
1,3-双(2,4,6-三甲基苯基)-4-[(三甲基氨基)甲基]咪唑烷-2-亚基]-(2-异丙氧基亚苄基)二氯化钌(II)六氟磷酸盐,StickyCatPF6, 1,3-Bis(2,4,6-trimethylphenyl)-4-[(trimethylammonio)methyl]imidazolidin-2-ylidene]-(2-i-propoxybenzylidene)dichlororuthenium(II) hexafluorophosphate StickyCat PF6