(R)-(+)-[(R)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane

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Technical Notes:

1.Ligand for copper-catalyzed asymmetric allylic alkylation of halocrotonates

2.L igand for silver-catalyzed asymmetric 1 ,3-dipolar cycloadditions of a-iminonitriles

3.L igand for copper- catalyzed enantioselective reductive couplings of alkenylazaarenes with ketones

4.L igand for copper-catalyzed chiral Mannich-type reactions of y-butenolides and N-thiophosphinoyl ketimines

5.L igand for palladium catalyzed asymmetric borylation

6.L igand for copper-catalyzed enantiodivergent hydroboration of bicyclic alkenes

References : 1.Adv. Synth. Catal. 2010, 352, 999. 2.Chem. Commun.. 2011, 47, 6784. 3.J. Am. Chem. Soc.. 2012, 134, 8428. 4.Angew. Chem. Int. Ed.. 2013, 52, 7310 5.Angew. Chem. Int. Ed.. 2013, 52, 8069. 6.Org. L ett., 2015, 17, 764.

Strem

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