Technical Notes:
1.Ligand for Rh-catalyzed asymmetric hydrogenation of a-acetamidoacrylates.
2. Ligand for Rh-catalyzed hydrogenation of a- and ß- enamides, acrylic acid derivatives, itaconates, ß-ketoesters and 1 ,3diketones.
3.Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives .
4.Ligand for lr-catalyzed asymmetric transfer hydrogenation of ketones.
5.Ligand for Cu-catalyzed e nantiosele ctive hydroboration of a- and ß-unsaturated esters and nitriles.
References: 1. Chem. Eur. J., 1998, 4, 950. 2.Tetrahedron-Asymmetr., 1999, 10, 37 5. 3.Tetrahedron-Asymmetr., 2004, 15, 2299. 4.Chem. Eur. J., 2006, 12, 5376. 5.Chem. Eur. J., 2008, 14, 1 0388. 6.Angew. Chem. Int. Ed., 2008, 47, 145.