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(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride

(1R,2R)-(-)-[1,2-环己二胺-N,N'-双(3,5-二叔丁基水杨基)]氯化锰

品牌
Strem
CAS
138124-32-0
货号
25-0300
包装型号
规格纯度
98%
参考价格
543 *本价格含增值税费
促销
数量
-+
产品介绍:

Technical Notes:

1.Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.

2.Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corres ponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.

3.As ymmetric Kinetic res olution of secondary alcohols in water.

4.Enantios elective Reformatsky reaction with ketones.

References:

1.J. Org. Chem.. 1993, 58, 6939.

2.J. Am. Chem. Soc., 1994, 116, 6937

3.Encyclopedia of Reagents for Organic Synthesis, 1995, 7, 4585.

4.Angew. Chem. Int. Ed. Eng., 2003, 42, 1042.

5.Angew. Chem. Int. Ed. Eng., 2006, 45, 2951.

Strem

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