(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl

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Technical Note

1.See 15-0042.

2.Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives

3.Ru- catalyzed asymmetric hydrogenation of ketones and alkenes.

4.Enantioselective copper-catalyzed asymmetric hydrosilylation of aryl ketones.

5.Synthesis of chiral 3-substituted indanones via an enantioselective reductive-Heck reaction.

6.Gold(1)- catalyzed enantioselective ring expansion of allenylcyclopropanols.

7.Conjugate addition using 2-heteroaryl titanates and zinc reagents .

References: 1. Adv. Synth. Catal., 2004, 346, 842. 2.Org. L ett., 2006, 8, 4573. 3.Org. Process Res. Devel., 2001, 5, 438. 4.J. Am. Chem. Soc., 2001, 123, 1291 7. 5.J. Org. Chem., 2007, 72, 9253. 6.J. Am. Chem. Soc., 2009, 131, 91 78. 7.Org. L ett., 2009, 11, 4200.

Strem

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