Technical Notes:
1. See 15-015
2.Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
3.Ligand for palladium-catalyzed a-arylation of ketones.
4.Ligand for Cu-catalyzed asymmetric conjugate reduction.
5.Ligand for Cu-catalyzed as ymmetric dienolate addition to aldehydes.
6. Enantios elective conjugate reduction of lactones and lactams.
7.Ligand used in the enantioselective cycloaddition of allenylsilanes with a-lmino esters .
8. Catalytic Aldol reaction to ketones .
9. Ligand with rhodium catalyses 2+2+ 2 cycloaddition reaction of alkenes and alkynes.
10. L igand used in the iridium-catalyzed enantios elective C-H bond activation of 2-( alkylamino)-pyridine with alkenes .
11. Iridium catalyzed regio-, diastereo -, and enantioselective tert- hydroxyl)- prenylation of alcohols.
12. Rhodium-catalyzed cross cyclotrimeriz ation.