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(2S)-2-[[[[(1R,2R)-2-Aminocyclohexyl]amino]thioxomethyl]amino]-N,3,3-trimethyl-N-(phenylmethyl)butanamide

(S)-2-[[(1R,2R)-2-氨基环己基]硫脲基]-N-苄基-N,3,3-三甲基丁酰胺

品牌
Strem
CAS
479423-21-7
货号
07-0956
包装型号
规格纯度
98%, (99% ee)
参考价格
1995 *本价格含增值税费
促销
数量
-+
产品介绍:

Technical Notes:

1.Conjugate Addition: Primary amine -thiourea derivative is an active and highly enantioselective catalyst for the conjugate addition of ketones to nitroalkenes.

2.Michael Addition: The asymmetric Michael addition of dioxindoles to ß-substituted nitroalkenes is reported. The bifunctional primary amine-thiourea, by means of a non-covalent-based mode of catalysis, secures

direct access to 3-substituted 3-hydroxyoxindole derivatives with high stereocontrol.

References:

1. J. Am. Chem. Soc., 2006, 128, 7170-7171.

2. Chem. Commun., 2012, 48, 3336-3338.

Strem

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