Technical Notes:
1.Cyclic Alkyl Amino Carbene (CAAC) ligand for ruthenium-catalyzed ethenolysis to cleave carbon- carbon double bonds.
2.Ligand for rhodium-catalyzed hydrogenation of readily available fluorinated arenes to form to all-cis- (multi )fluorinated cyclo alkanes.
References: 1. Angew. Chem. Int. Ed., 2015, 54, 1919. 2. Science, 201 7, 357, 908.