产品介绍：
产品说明
应用
Dimethyl propargylmalonate can be used as a reactant to synthesize:
- Nitro methylenecyclopentanes by [3+2] annulation reaction with various nitroalkenes in the presence of Triton B.
- Propargylmalonamides intermediates, applicable in the preparation of ″click BOX″ ligands by copper-catalyzed cycloaddition and oxazoline ring formation reaction.
- Cyclopentene derivatives by reacting with various α, β-unsaturated ketones using a combination of organocatalysts and transition metal catalysts.
包装
10, 50 mL in glass bottle
基本信息
| 线性分子式 | HC≡CCH2CH(COOCH3)2 |
| 分子量 | 170.16 |
| Beilstein | 3539408 |
| MDL编号 | MFCD00077856 |
| PubChem化学物质编号 | 57652893 |
| NACRES | NA.22 |
产品性质
| 测定 | ≥95.0% (GC) |
| 折射率 | n |
| bp | 93-95 ℃/7 mmHg (lit.) |
| 密度 | 1.119 g/mL at 20 ℃ (lit.) |
| SMILES string | COC(=O)C(CC#C)C(=O)OC |
| InChI | 1S/C8H10O4/c1-4-5-6(7(9)11-2)8(10)12-3/h1,6H,5H2,2-3H3 |
| InChI key | PWQAXFWWMXTVFT-UHFFFAOYSA-N |
安全信息
| 储存分类代码 | 10 - Combustible liquids |
| WGK | WGK 3 |
| 闪点(F) | 235.4 °F - closed cup |
| 闪点(C) | 113 ℃ - closed cup |
| 个人防护装备 | Eyeshields, Gloves |
