产品说明
一般描述
(S)-SDP is a chiral diphosphine reagent used in the asymmetric hydrogenation of ketones catalyzed by transition metal. It is also used in hydrosilylation or cyclization of 1,6-enynes.
应用
(S)-SDP can be used:
- As a ligand in the ruthenium-catalyzed asymmetric hydrogenation of cyclic ketones to give cycloalkanols.
- To prepare ruthenium complexes, which are used in the asymmetric hydrogenation of different prochiral ketones.
包装
50 mg in amber glass bottle
基本信息
经验(实验)分子式 | C41H34P2 |
分子量 | 588.66 |
MDL编号 | MFCD08459344 |
PubChem化学物质编号 | 329762227 |
NACRES | NA.22 |
产品性质
测定 | ≥95% |
旋光性 | [α]22/D −191°, c = 1 in chloroform |
mp | 199-204 ℃ |
储存温度 | −20℃ |
SMILES string | C1CC2(CCc3cccc(P(c4ccccc4)c5ccccc5)c23)c6c1cccc6P(c7ccccc7)c8ccccc8 |
InChI | 1S/C41H34P2/c1-5-17-33(18-6-1)42(34-19-7-2-8-20-34)37-25-13-15-31-27-29-41(39(31)37)30-28-32-16-14-26-38(40(32)41)43(35-21-9-3-10-22-35)36-23-11-4-12-24-36/h1-26H,27-30H2 |
InChI key | DKZNVWNOOLQCMJ-UHFFFAOYSA-N |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | Eyeshields, Gloves, type N95 (US) |