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SLAP TM

品牌
Sigma-Aldrich
CAS
1226877-72-0
货号
900814
包装型号
规格纯度
≥95%
参考价格
1233.03 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

When used with aliphatic or aromatic aldehydes, this silicon amine protocol (SLAP) reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)2dtbbpy]PF6 ((747769) is used with a recommended starting combination of Lewis acids Bi(OTf)3 (633305) and Cu(OTf)2 (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.

包装

500 mg in glass insert

其他说明

  • Technology Spotlight: SLAP Reagents for Piperazine Synthesis
  • Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
  • Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
  • Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

基本信息

经验(实验)分子式C6H17NSSi
分子量163.36
NACRESNA.22

产品性质

质量水平100
测定≥95%
形式liquid
折射率n/D 1.4811
密度0.90746 g/mL
储存温度2-8℃
SMILES stringNCCSC[Si](C)(C)C

安全信息

储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)174.0 °F
闪点(C)78.89 ℃

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