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SLAP 2,3-Bicyclo-(3,4-THF) N-BnPip Reagent

品牌
Sigma-Aldrich
货号
900401
包装型号
规格纯度
≥95%
参考价格
1373.81 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)2dtbbpy]PF6 (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.

包装

500 mg in amber glass bottle

其他说明

  • Technology Spotlight: SLAP Reagents for Piperazine Synthesis
  • Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
  • Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
  • Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

基本信息

经验(实验)分子式C15H26N2OSi
分子量278.47
NACRESNA.22

产品性质

质量水平100
测定≥95%
形式liquid
折射率n/D 1.520
密度1.000 g/mL
储存温度−20℃

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3

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