产品介绍：
产品说明
应用
The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.
其他说明
- Technology Spotlight: Jamison Nickel (II) Precatalysts
- A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes
法律信息
Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.
基本信息
| 经验(实验)分子式 | C51H39ClNiP2 |
| 分子量 | 807.95 |
产品性质
| 质量水平 | 100 |
| 形式 | powder or solid |
| reaction suitability | core: nickel reagent type: catalyst |
| mp | >300 ℃ |
| SMILES string | Cl[Ni]1(P(C2=C([H])C([H])=C([H])C([H])=C2[H])(C3=C([H])C([H])=C([H])C([H])=C3[H])C(C([H])=C4[H])=[C@@]([C@@]5=C(P1(C6=C([H])C([H])=C([H])C([H])=C6[H])C7=C([H])C([H])=C([H])C([H])=C7[H])C([H])=C([H])C8=C5C([H])=C([H])C([H])=C8[H])C9=C4C([H])=C([H])C([H])=C |
安全信息
| 储存分类代码 | 4.1B - Flammable solid hazardous materials |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
