产品介绍：
产品说明
应用
Catalyst for:
- [4C+2C] cycloadditions
- Cis-selective single-cleavagte skeletal cycloisomerization
- Diastereoselective Au-catalyzed intermolecular cyclopropanation
- Elucidating the mechanism of "endocyclic" skeletal rearrangement of 1,6-enynes
- Addition reactions
Gold Catalysts — 21st Century ′Gold Rush′
- Intermolecular addition of carbon nucleophiles to 1,5 and 1,6 enynes
包装
500 mg in glass bottle
基本信息
| 经验(实验)分子式 | C42H63AuClO3P |
| 分子量 | 879.34 |
| MDL编号 | MFCD11045473 |
| PubChem化学物质编号 | 329762147 |
| NACRES | NA.22 |
产品性质
| 形式 | powder |
| 质量水平 | 100 |
| reaction suitability | core: gold reagent type: catalyst |
| mp | 200-202 ℃ |
| SMILES string | Cl[Au].CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C |
| InChI | 1S/C42H63O3P.Au.ClH/c1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18;;/h19-27H,1-18H3;;1H/q;+1;/p-1 |
| InChI key | GCWCLHMEYZKZRO-UHFFFAOYSA-M |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 - H319 - H335 |
| 预防措施声明 | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
