产品说明
应用
Developed in the Engle lab, this 2,2′-bipyridylamide (PPA) is a pincer-like, removable tridentate directing group that stabilizes 6-membered palladacycles for olefin functionalization. Together with similar ligand PAQ (901250), researchers demonstrated regioselective remote hydrocarbofunctionalization of alkene-containing substrate classes (e.g. 4-pentenoic acids, allylic alcohols, homoallyl amines, bis-homoallylamines) using Pd(II) catalysis.
其他说明
Tridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene Hydrofunctionalization
基本信息
经验(实验)分子式 | C11H8N2O2 · xHCl |
分子量 | 200.19 (free base basis) |
MDL编号 | MFCD11100046 |
产品性质
质量水平 | 100 |
形式 | powder or crystals |
reaction suitability | reagent type: ligand reaction type: C-H Activation |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |