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2-Cyanobenzylzinc bromide solution

2-氰苄基溴化锌 溶液

品牌
Sigma-Aldrich
CAS
199465-66-2
货号
520322
包装型号
规格纯度
0.5 M in THF
参考价格
3258.95 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

2-Cyanobenzylzinc bromide can be used as a reactant:

  • In the metal-catalyzed Negishi cross-coupling reactions to prepare aryl or heteroaryl derivatives via carbon-carbon bond formation.
  • To synthesize 4-(2-Cyanobenzyl)-3′-(trifluoromethyl)biphenyl by reacting with aryl nonaflate in the presence of Pd(dba)2 as a catalyst.
  • To prepare 2-[(2-cyanophenyl)methyl] benzamide by treating with 2-iodobenzamide using a nickel catalyst.

包装

50 mL in Sure/Seal™

法律信息

Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标

基本信息

线性分子式NCC6H4CH2ZnBr
分子量261.43
MDL编号MFCD01311397
PubChem化学物质编号24874105

产品性质

浓度0.5 M in THF
密度0.993 g/mL at 25 ℃
储存温度2-8℃
SMILES stringBr[Zn]Cc1ccccc1C#N
InChI1S/C8H6N.BrH.Zn/c1-7-4-2-3-5-8(7)6-9;;/h2-5H,1H2;1H;/q;;+1/p-1
InChI keyLQRNYQAXNZETFP-UHFFFAOYSA-M

安全信息

象形图GHS02GHS07GHS08
警示用语:Danger
危险声明H225 - H319 - H335 - H336 - H351
预防措施声明P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313
危险分类Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2
补充剂危害EUH014 - EUH019
储存分类代码4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGKWGK 3
闪点(F)1.4 °F - closed cup
闪点(C)-17 ℃ - closed cup

Sigma-Aldrich

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