产品说明
应用
[1,2-Bis(diphenylphosphino)ethane]dibromonickel(II) is a catalyst for a variety of transformations, including:
- kumada catalyst-transfer polycondensation
- oxidation of carboranyl phosphine ligands
- synthesis of nickel-iron dithiolato hydrides
- hydroformylation of alcohols
- Ullmann reactions - homocoupling reactions
- intramolecular aerobic oxidative amination of alkenes
其他说明
Synthesis of Highly Substituted Isoquinolone Derivatives by Nickel-Catalyzed Annulation of 2-Halobenzamides with Alkynes
基本信息
经验(实验)分子式 | C26H24Br2NiP2 |
分子量 | 616.92 |
产品性质
测定 | ≥95% |
形式 | powder |
mp | 322-326 ℃ |
InChI | 1S/C26H24P2.2BrH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2 |
InChI key | AEGMSHMBRVOLMV-UHFFFAOYSA-L |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H317 - H334 - H341 - H350i - H360D - H372 - H410 |
预防措施声明 | P201 - P273 - P280 - P302 + P352 - P308 + P313 |
危险分类 | Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 |
储存分类代码 | 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |