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[1,2-Bis(diphenylphosphino)ethane]dibromonickel(II)

品牌
Sigma-Aldrich
CAS
14647-21-3
货号
913278
包装型号
规格纯度
≥95%
参考价格
1904.37 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

[1,2-Bis(diphenylphosphino)ethane]dibromonickel(II) is a catalyst for a variety of transformations, including:

  • kumada catalyst-transfer polycondensation
  • oxidation of carboranyl phosphine ligands
  • synthesis of nickel-iron dithiolato hydrides
  • hydroformylation of alcohols
  • Ullmann reactions - homocoupling reactions
  • intramolecular aerobic oxidative amination of alkenes

其他说明

Synthesis of Highly Substituted Isoquinolone Derivatives by Nickel-Catalyzed Annulation of 2-Halobenzamides with Alkynes

基本信息

经验(实验)分子式C26H24Br2NiP2
分子量616.92

产品性质

测定≥95%
形式powder
mp322-326 ℃
InChI1S/C26H24P2.2BrH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChI keyAEGMSHMBRVOLMV-UHFFFAOYSA-L

安全信息

象形图GHS08GHS09
警示用语:Danger
危险声明H317 - H334 - H341 - H350i - H360D - H372 - H410
预防措施声明P201 - P273 - P280 - P302 + P352 - P308 + P313
危险分类Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

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